Determination of alkalinity in the given water sample.
Determination of temporary and permanent hardness in water sample using EDTA as standard solution.
Determination of available chlorine in bleaching powder.
Determination of chloride content in the given water sample by Mohr’s method.
Determination of iron content in the given ore by using external indictor
pH-metric titration.
Determination of Equivalent weight of Iron by the chemical displacement method. The equivalent weight of copper is 63.5
(Note : the procedure to be followed in carrying the above experiment is given as annexure)
Viscosity of an addition polymer like polyster by Viscometer.
Determination of iron concentration in sample of water by colorimetric method. The method involves the use of KCNS as colour developing agent and the measurements are carried out at l max 480 nm.
Note : The general procedure of estimation is given on pp653-8 of the textbook of Quantitative Chemical Analysis by A.I. Vogel 6th Edition, Publisher : Pearson education Ltd. 2000)
Element detection & functional group identification in organic compounds
Annexure
In this experiment we will determine the equivalent weight of Iron, which displaces one equivalent of copper (63.5 g) from a solution containing copper ions.
Procedure: Clean a sample of iron (strip measuring 3.5cm×1.5cm) with a sand paper and weigh it accurately. Place it in a clean beaker (250ml) and pour into it 100ml of CuSo4 solution of known strength (~ N/10) Allow the strip to stand in the beacker for about 30 minutes. Carefully withdraw the strip of iron (from the beaker) with a forceps and place it on a porcelain plate contained in a desiccafor (using cacl2 as a desiccant ). The quantity of copper sulphate remaining in solution – after the chemical displacement, is estimated by lodometric titration method. The dried strip of iron (containing the deposited copper) is then carefully weighed.
Observations:
Weight of iron strip = …………….g
Wt. Of iron strip + copper = ………………g
(after drying )
wt. of copper deposited on iron strip Þ
Initial conc. of cu- final conc. of cu. (determined by titration)
The weight of iron, which goes into solution(as Fe So 4)
Þ ( Initial weight of iron strip + weight of deposited copper) - weight of iron strip along with copper (after drying)
Eq.wt. of copper (63.5) = Wt. of Copper Deposited
Eq. Wt. of Iron Wt. of Fe(s) (going into solution)
The Eq. Wt. of Fe = ?
The % error involved in the experiment =……………….
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