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Unit – I |
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1.Molecular theory of diatomic heteromolecules, Bond theory of bonding in metals, Hydrogen bonding. |
| 2.Solid state Chemistry: |
Radius Ratio Rule, Space lattice (only cubes), Type of unit cell, Bragg’s Law, Calculation of Density of unit cell.
One & Two Dimensional solids, graphite as two dimensional solid and its conducting properties. Fullerene & its applications. |
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Unit – II |
| 1.Basic principles of spectroscopic methods. The use of UV, Visible, IR, 1H NMR, for the determination of structure of simple organic compounds. |
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2.Characteristics and classification of polymers.
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| 3.Structures of the following polymers, viz, Natural and synthetic rubbers, Polyamide and Polyester fibres, polymethylmethacrylate, poly acrylonitrile and polystyrene. A brief account of conducting polymers (polypyrrole & polytiphene) & their applications.
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| Unit – III |
1.Stability of reaction intermediates, e.g. Carbanion, Carbocation and free radicals. Types of organic reactions, & Mechanism of nucleophilic substitution reaction. |
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2.Mechanism of the following reactions. |
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(i) Aldol condensation. (ii) Cannizzaro reaction (iii) Beckmann rearrangement (iv) Hofmann rearrangement, and
(v) Diels-Alder reaction |
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| 3.E-Z Nomenclature. Optical Isomerism of organic Compounds containing one chiral center. Examples of optically active compounds without chirality. Conformations of butane. |
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Unit – IV |
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1. Order & Molecularity of reactions. First & Second order reactions. Energy of activation. |
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| 2. Phase Rule: Its application to one component system (Water). |
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3. Equilibrium Potential, electrochemical cells (galvanic & concentration cells), Electrochemical theory of corrosion & protection of corrosion. |
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Magnetic Properties of Materials |
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Basic Concept of Para- , Dia and Ferro-Magnetism, Langevin’s Theory of Diamagnetism, Phenomenon of Hysterisis and Its Applications |
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Unit – V |
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1. Hardness of water, softening of water by Lenny-S process & Reverse osmosis. Treatment of boiler feed water by Calgon process, Zeolites and ion-exchange resins.
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2. Classification of fuels, Coal, Biomass & Biogas. Determination of gross and net calorific values using Bomb Calorimeter. |
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| 3. Environmental pollution : Types of pollution & pollutants, Air Pollution. Formation and depletion of ozone, smog and Acid rain. |
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References: |
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Organic Chemistry (Morrison & Boy)
Inorganic Chemistry (I.D. Lee)
Physical Chemistry (Barrow)
Environmental chemistry (Manahan)
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